AGROSAR® 360 SL 1L | 5L

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40,57  - 81,22 inkl. MwSt. zzgl. Versandkosten

AGROSAR 360 SL is a herbicide in the form of a concentrate for the preparation of an aqueous solution. Use it foliar to control couch grass and other monocotyledonous and dicotyledonous weeds (annual and perennial) before harvesting winter wheat and winter oilseed rape. Use after harvest and before post-harvest cultivation in apple, pear, cherry, plum, peach, apricot, gooseberry, chokeberry, black, red and white currants, in forest nurseries, when planting and reforesting Scots pine and deciduous tree species, in gardens, in allotments, around houses, along fences, on driveways.

AGROSAR 360 SL  OPTIMAL PRODUCT IN TERMS OF USER SAFETY AND PROTECTION OF THE ENVIRONMENT

The advantage of AGROSAR 360 SL over many other similar products is that it does not contain ethoxylated fatty amine (tallow amine), which is commonly used as an adjuvant in this type of formulation. In AGROSAR® 360 SL, the ethoxylated fatty amine has been replaced by a new generation internal adjuvant which, together with other surfactants, forms a unique system that supports the action of the active ingredient by optimizing the adhesion of the spray droplet to the leaf surface and covering the surface of the leaf blade better and more uniformly with the working fluid, which contributes to the maximum exploitation of the active ingredient potential by increasing the penetration area.

It should be emphasized here that the additives in a product influence its quality, effectiveness, shelf life and the lack of toxicity of the preparation. The frequently used ethoxylated fatty amine (tallow amine) has specific toxicological effects on aquatic organisms. The substitution of tallow amine by the use of a new generation of adjuvants has significantly improved the toxicological properties of AGROSAR 360 SL and its classification, particularly with regard to ecotoxicology and environmental impact.

The adjuvant used in the product AGROSAR 360 SL is a mixture that does not contain any substances that are considered to be very persistent or highly bioaccumulative (so-called PBT or vPvB).

In terms of environmental toxicology, AGROSAR 360 SL is not classified as "dangerous for the environment" and is therefore not labeled with the GHS 09 pictogram (according to Regulation (EC) No 1272/2008 of 16 December 2008 on classification, labeling and packaging of substances and mixtures) or the hazard symbol "N" (according to the "old" classification), which distinguishes it from glyphosate-containing products available on the market.

 

 

Item number N/A Category:
Cultivation Combating agrophages    ... Agrophages attack plants and lead to their death ...
How is it used? Dosage
Railroad tracks Ribwort plantain, cocksfoot, common bulrush, red bulrush, common mugwort, cornflower, orchid, swallowtail, field mustard, starflower, common spirea, buttercup, carmine buttercup, white meadow-grass, field clover, yarrow, cocksfoot, common fern, common milkwort, dandelion, Canada goldenrod, creeping thistle, common oat-grass, common couch-grass, common couch-grass, Common coltsfoot, Common nettle, Field bindweed, Persimmon fern, Three-leaved fern, Canada creeper, Field horsetail, Common foxglove, Common bugleweed, Common chamomile, centaury, amaranth, field sorrel, blunt-leaved sorrel, wood sorrel, yellow sorrel, common hellebore, field bindweed, annual panicle, green orchid, common vetch, narrow-leaved vetch. Maximum/recommended dose for a single application: 7.5 l/ha.
Gooseberry, chokeberry, blackcurrant, redcurrant, whitecurrant, pear, peach, cherry, apricot, plum, cherry Lanceolate bulrush, common bulrush, lesser cinquefoil, common mugwort, cornflower, uniflorous orchid, field violet, field mustard, common starflower, common spirea, purple buttercup, White balsam, white clover, cocksfoot, common cocksfoot, common poppy, liverwort, field milkwort, dandelion, Canada goldenrod, dew-oat, common hornwort, cocksfoot, tufted bulrush, Japanese cattail, Canada bindweed, hornwort, common bugleweed, common chamomile, common bulrush, common centipede, common elder, amaranth, Yellow sorrel, field sorrel, blunt sorrel, wood sorrel, field columbine, field bindweed, annual bluegrass, glandular willow, trichomonium, common vetch, narrow-leaved vetch, field horsetail Maximum dose for single application: 8.0 l/ha.
Recommended dose for single application: 3.0 - 8.0 l/ha.
Maximum dose for single application: 80.0 ml/100 m2.
Recommended dose for single application: 30.0 - 80.0 ml/100m2.
Forest nurseries, regeneration, afforestation One-sided orchid, Chickweed, White bentgrass, Field poppy, Common fern, Canada bindweed, Common bindweed, Common centaury, Common bulrush, Annual panicle Maximum dose for single application: 3.0 l/ha.
Recommended dose for single application: 2.0-3.0 l/ha.
Apple tree Ribwort plantain, cocksfoot, common bulrush, common mugwort, cornflower, monocot, field violet, field mustard, common starflower, common bulrush, purple loosestrife, white goosefoot, White clover, Cocksfoot, Corn poppy, Wood anemone, Common milkwort, Dandelion, Canada goldenrod, Dew-oat, Common stilt, Common couch grass, Three-leaved orchid, Canadian clover, knotweed, hornwort, common chamomile, common knotweed, common greenshank, rough amaranth, yellow sorrel, field sorrel, blunt sorrel, wood sorrel, columbine, field bindweed, annual meadow-grass, glandular willow, green hogweed, common vetch, narrow-leaved vetch, field horsetail, persimmon fern, field bindweed, common radish, soft clubroot, small-flowered yellowthread Maximum dose for single application: 8.0 l/ha.
Recommended dose for single application: 3.0 - 8.0 l/ha.
Maximum dose for single application: 80.0 ml/100 m2.
Recommended dose for single application: 30.0 - 80.0 ml/100m2
Winter oilseed rape, winter wheat Field violet, white comose, corn poppy, common fern, common bulrush, common bindweed, broad-leaved bindweed, common bindweed, common chickweed, Canadian puke, common fern, annual panicle Maximum/recommended dose for a single application: 4.0 l/ha.
Gardens, plots of land, land around the house, sidewalks, driveways Ribwort plantain, cocksfoot, common bulrush, red bulrush, common mugwort, cornflower, thale cress, swallowtail, field mustard, common starflower, common spirea, buttercup, crimson buttercup, white meadow-grass, field clover, yarrow, cocksfoot, common fern, common milkwort, dandelion, Canada goldenrod, creeping thistle, common oat-grass, common couch-grass, common couch-grass, common coltsfoot, common nettle, field bindweed, field bindweed, common cocksfoot, three-leaved couch grass, Canada creeper, orchid, lesser centaury, common bugleweed, common chamomile, centaury, rough amaranth, field sorrel, blunt-leaved sorrel, wood sorrel, yellow sorrel, common hellebore, field bindweed, annual panicle, green trichome, common vetch, narrow-leaved vetch. Maximum dose for single application: 7.5 l/ha.
Recommended quantity for a single application: 5.0 - 7.5 l/ha.
Maximum dose for single application: 75.0 ml/100 m2.
Recommended dose for single application: 50.0 - 75.0 ml/100 m2.

 

AGROSAR® 360 SL      IN THE LIGHT OF NEW CHALLENGES FOR AGRICULTURE

Today's world, in which a constantly growing population requires the provision of more and more food, poses new challenges for agriculture in particular. Agricultural production must be constantly intensified, especially in view of the decreasing amount of arable land (due to soil erosion, among other things). The European Union is currently pursuing a policy of integrated pest management, in which all available plant protection methods are used in such a way that the risks to humans, animals and the environment are minimized.

Integrated pest management involves the rational use of suitable pesticides, which have become an integral part of modern crop production. One of the many crop protection products offered by CIECH Sarzyna S.A. is AGROSAR® 360 SL (herbicide with 360 g/l glyphosate).

AGROSAR® 360 SL      OPTIMAL PRODUCT IN TERMS OF QUALITY AND EFFECTIVENESS

The raw material base of AGROSAR® 360 SL consists of:

  • High-quality active ingredient material with at least 98 % glyphosate,
  • internal adjuvant of the next generation,
  • an arrangement of surfactants to ensure the appropriate physico-chemical properties of the preparation.

The raw materials used in production must meet the quality requirements specified for each individual raw material and confirmed by the central analysis laboratory if they are approved for production. During the production process, their correctness in the individual process stages is checked by so-called in-process analyses. The final product is released on the basis of certificates of analysis, which are issued separately for each batch by the central analysis laboratory.

The right quality of the preparation is clearly reflected in its effectiveness through the right choice of the system: active substance - adjuvant. The appropriate effectiveness of the preparation has been confirmed by numerous studies carried out in various regions, e.g. by the Institute of Soil Science and Plant Cultivation in Puławy, the Plant Protection Institute in Poznań and the Horticultural Institute in Skierniewice. A total of 28 tests on biological efficacy and phytotoxicity were carried out on registered plants.

Ciech Logo Agrofluid  

SAFETY DATA SHEET

No.: KCh/H/56
 

®AGROSAR 360 SL

Issue: 5
Publication date: 25.01.2021
Date of the 1st edition:

27.02.2014

Replaced: KCh/H/56, issue 4 from 04.08.2020 Page 1 from 13

 

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product identifier
Trade name:              ®AGROSAR 360 SL

Chemical name: not applicable (the product is a mixture)
EC number: not applicable

Registration number: Mixture - not subject to registration under REACH.
UFI code: DV00-00RU-300R-FXT8
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses:

Plant protection product for professional and non-commercial users with herbicidal activity in the form of a concentrate for the preparation of an aqueous solution intended for the control of couch grass and other mono- and dicotyledonous weeds (annual and perennial).

Uses advised against: all other than those mentioned above

1.3 Details of the supplier of the safety data sheet
Supplier: CIECH SARZYNA SPÓŁKA AKCYJNA
Address: ul. Chemików 1, 37-310 Nowa Sarzyna, Poland
Phone/Fax: + 48 (17) 2407 416 between 7 a.m. and 3 p.m.

+ 48 (17) 2407 122

E-mail address of the person responsible for the safety data sheet: [email protected]
1.4 Emergency numbers (POLAND)
998 (fire department), 999 (ambulance), 112 (emergency telephone),
 

Section 2: Possible dangers

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (as amended)*.

Skin Sens. 1 - Skin sensitization category 1.

H317 - May cause an allergic skin reaction.

Aquatic Chronic 3 - Chronic water hazard, category 3.

H412 - Harmful to aquatic life with long lasting effects.

2.2 Labeling elements
Hazard pictograms and signal word

2x Professional Rat Mice Rodent Bait Station Bait Box +100g bait pre-portioned

NOTE

(Pictogram - black symbols on a white background with a red border)
Product identifier
®AGROSAR 360 SL

The product includes:

Glyphosate in the form of isopropylamine salt (a substance from the group of phosphonic acid derivatives)

Hazard warnings:
              H317- May cause an allergic skin reaction.

              H412- Harmful to aquatic life with long lasting effects.

EUH401 - To avoid risks to human health and the environment, follow the instructions for use.

Safety instructions:
P261 - The Avoid inhalation of spray.

P272 - Do not wear contaminated protective clothing outside the workplace.

P280 - Wear protective gloves.

P302+P352 - IF ON SKIN: Wash with plenty of water.

P333+P313 - In case of skin irritation or rash: Seek medical advice/attention.

P362+P364 - Remove contaminated clothing and wash before reuse.

2.3 Other risks
The components of the mixture do not meet the criteria for classification as PBT or vPvB in accordance with Annex XIII of REACH.
The components of the mixture do not exhibit endocrine disrupting properties according to the criteria of Commission Regulation (EU) 2017/2100 (3) or Commission Regulation (EU) 2018/605 (4).
 

S e c t i o n 3: SUMMARY/DISCLOSURE OF COMPONENTS

3.1 Fabrics
Not applicable.

 

3.2 Mixtures

Substance1): Contents

[%]

Classification according to

of Regulation (EC)

No. 1272/20082)

Isopropylamine salt of the N-(Phosphonomethyl)-glycine1)

 

CAS number: 38641-94-0

EC number: 254-056-8

Index number: 015-184-00-8

Registration number: not applicable (Art. 15 of the REACH Regulation)

 

 

 

 

42 ± 2

 

 

 

 

Aquatic Chronic 2    H411

C12-14-alkyl dimethyl betaines

CAS number: 66455-29-6

EC number: 931-700-2

Registration no.: 01-2119529251-48-xxxx

 

 

3,2

 

Skin corr. 1B                H314

Eyes 1                          H318

Aquatic Chronic 3          
H412

  • - Classification of the substance according to Table 3.1 of Regulation No. 1272/2008 - see section 15.1
  • - The full wording of the abbreviations, symbols and H-phrases is listed in section 16 of this data sheet.

 

Section 4: FIRST AID MEASURES

  • Description of first aid measures

General information: Remove the victim from the danger zone. Place the affected person in the recovery position and transport them. Take off contaminated clothing immediately and remove safely.
In case of contact with skin: Remove contaminated clothing and shoes immediately. Wash contaminated skin thoroughly with soap and water. If symptoms of irritation/sensitization occur, consult a doctor.

Eye contact: Protect non-irritated eyes, remove contact lenses. Rinse contaminated eyes thoroughly with water for 10-15 minutes. Avoid strong water jet - risk of corneal damage. After rinsing, apply a sterile dressing. Seek medical advice, preferably from an ophthalmologist.

If swallowed: Call a doctor immediately, show the packaging or label. Do not induce vomiting. Rinse mouth thoroughly with water, then drink plenty of water. Never put anything in the mouth of an unconscious person.

After inhalation: Remove victim to fresh air, keep warm and rest. If any worrying symptoms occur, consult a doctor.

4.2 Most important symptoms and effects, both acute and delayed

Skin contactSensitive persons may experience redness, dry skin, itching, rash or other skin changes.

In case of contact with the eyesRedness, tearing, burning and pain possible.

After ingestionPossible irritation of the gastrointestinal tract, abdominal pain and nausea.

4.3 Information on immediate medical assistance or special treatment

The decision on how to proceed with the rescue should be made by the doctor after a thorough assessment of the victim's condition. Monitor cardiac and circulatory functions. No antidote. Apply symptomatic treatment.
 

Section 5: FIRE-FIGHTING MEASURES

5.1 Fire extinguishing agent
Suitable extinguishing agents: Diffuse water jet, foam, carbon dioxide and extinguishing powder. Adapt the extinguishing agent to the substances stored in the vicinity.

Unsuitable extinguishing agents: Compact water jet.

5.2 Special hazards arising from the substance or mixture
Hazardous vapors and gases containing carbon, nitrogen and phosphorus oxides may form during the combustion of materials stored with the product. Avoid inhaling the combustion products as they may be hazardous to health.
5.3 Information for the fire department
General protective measures in case of fire. Do not remain in the fire area without suitable clothing. Recommended personal protective equipment for rescue services: full protective suit, insulating breathing apparatus. Handling extinguishing water as described in section 6.2.
 

Section 6: MEASURES IN CASE OF ACCIDENTAL RELEASE

6.1 Personal precautions, protective equipment and emergency procedures
For personnel not responsible for emergenciesRestrict bystander access to the accident area until the appropriate cleanup work has been completed. Use personal protective equipment. Avoid contamination of skin and eyes. Ensure adequate ventilation.
For the elimination of the consequences of the accidentEnsure that only trained personnel carry out the removal of the accident and its consequences. Wear protective clothing and chemical-resistant personal protective equipment.
6.2 Precautionary measures for the environment
If large quantities of the mixture are spilled, take measures to prevent it from spreading into the environment - prevent it from entering drains, watercourses, rivers, groundwater and soil. Notify the relevant emergency services. Warn others of the danger. Similar precautions should be taken in the event of extinguishing water (section 5).
6.3 Methods and material for containment and cleaning
In the case of large spills, bundle the resulting mixture and pump it into suitable, sealed and labeled containers for recycling or disposal in accordance with the Waste Act. Use absorbent kits to remove residues and small quantities of the spilled mixture or, failing that, use diatomaceous earth or sand. Collect the absorbent containing the mixture in suitable sealed and labeled waste containers and dispose of it in accordance with the Waste Act.
6.4 References to other sections
For handling of product waste, see section 13 of this sheet.

For personal protective equipment, see section 8 of this sheet.

 

Section 7: HANDLING AND STORAGE

7.1 Protective measures for safe handling
The relevant safety and hygiene regulations must be observed during handling. Avoid contamination of eyes and skin. Avoid inhalation of the sprayed liquid. Remove contaminated clothing and protective equipment before entering eating areas. Wash hands with soap and water before breaks and after work. Keep containers with the mixture tightly sealed. Ensure effective exhaust ventilation in work areas.
7.2 Conditions for safe storage, taking into account incompatibilities
Store in the hermetically sealed original packaging in dry and well-ventilated rooms at temperatures between 0 and 300°C. Do not store near foodstuffs, animal feed or food, out of the reach of unauthorized persons, especially children. Protect from sunlight and moisture.

Dispose of the unused product in a waste collector.

It is prohibited to use empty plant protection product packaging for other purposes.

Observe the regulations, rules and recommendations for the storage of crop protection products. Take all necessary measures to prevent accidental release of the mixture into drains, watercourses, rivers or the ground through unsealed packaging or transfer systems.

 

Suitable packaging material: Glass, polyethylene or non-galvanized hard steel sheet. Shelf life of the mixture: 2 years.

7.3 Specific end uses
The mixture is a plant protection product with herbicidal effect. When carrying out plant protection treatments with the product, the instructions on the label and the instructions for use in the sales packaging must be observed.

When preparing the mixture, the information in the safety data sheet and in the instructions applicable to the process must be observed.

 

Section 8: LIMITATION AND MONITORING OF EXPOSURE/PERSONAL PROTECTIVE EQUIPMENT

8.1 To be monitored Parameters
The maximum permissible concentrations of substances in the working environment in Poland for the substances listed in section 3.2 of the safety data sheet are not specified in Annex No. 1 to the Regulation of the Minister of Family, Labour and Social Policy of 12 June 2018 on the maximum permissible concentrations and intensities of factors harmful to health in the working environment (Journal of Laws of 2018, item 1286, as amended).
8.2 Exposure controls and monitoring
Observe safety and hygiene regulations. Wear the personal protective equipment as described in section

8.2.2 Do not eat, drink or smoke while working. Wash hands thoroughly with soap and water before breaks and at the end of work.

8.2.1 Appropriate technical control measures
Procedures for monitoring concentrations of hazardous components in the air and procedures for controlling air purity in the workplace should be applied - if available and justified in the given workplace - in accordance with appropriate reference methods - standards applicable in Poland. The mode, type and frequency of tests and measurements should comply with the requirements of the Regulation of the Minister of Health of February 2, 2011 on tests and measurements of factors harmful to health in the working environment (Journal of Laws No. 33, item 166, as amended).
8.2.2 Individual protective measures such as personal protective equipment
The personal protective equipment used should comply with the national requirements of Regulation (EU) 425/2016.

The employer is obliged to provide protective equipment suitable for the activities carried out and to maintain and clean it.

(a) Eye or face protection

Wear safety goggles or face protection.

(b) having the qualifications required for persons purchasing plant protection products specified in Article 28. Skin protection
Hand protection

Use suitable chemical-resistant protective gloves with a minimum thickness of 0.4 mm that have been tested in accordance with EN 374 - e.g. neoprene.

Protection of the body

Wear suitable protective clothing and shoes for the activity. Wash contaminated clothing regularly.

c) Protection of the airways

Personal respiratory protection is not required if the workplace is well ventilated. Otherwise, respirators or masks with filters should be used to absorb the vapors of organic compounds.

d) Thermal hazards
Type of protective equipment : Not applicable; the material does not present a thermal hazard.
8.2.3 Limiting and monitoring environmental exposure
In order to limit the effects on the environment and human health, the recommendations of this safety data sheet as well as the label and instructions for use of the product must be observed. When handling the product, use effective ventilation systems equipped with devices that prevent the emission of vapors of organic compounds into the ambient air. Do not allow the product or its packaging to enter water. Prevent the product or its packaging from entering drains, water reservoirs, rivers, groundwater and soil. It is forbidden to recycle or neutralize the product, its packaging and packaging waste outside the designated facilities or devices that meet the requirements of the Waste Act.

 

9.1 Information on the basic physical and chemical properties
Physical state: clear liquid

 

Color: clear to slightly yellow

Odor: light, characteristic of amines

Melting/freezing point : < -10 oC

Initial boiling point : > 100 oC

Flammability of materials:not applicable Lower and upper explosion limits:not labeled Flash point> 100oC

Auto-ignition temperature: not determined

Decomposition temperature: not applicable

pH value of a 1 %iger rhubarb 4.3

inematic viscosity:not determined Solubility (values for glyphosate): Water: 10.5 g/l at pH 2

Toluene: 0.036 g/l

Acetone: 0.078 g/l

Methanol: 0.231 g/l

Partition coefficient: n-octanol/water: log Pow= - 3.2 (at pH 7); Temp. 25oC (value

for glyphosate*)

(* Literature data, value based on survey)

Vapor pressure (25oC): 1.31 x 10-5 Pa (value for glyphosate)

absolute density (20oC): approx. 1.165 g/cm3

Relative vapor density: not determined

Particle properties: not applicable

9.2 Other information
9.2.1 Information on physical hazard classes
Not applicable.
9.2.2 Other security features
Surface tension (25oC): 25.9 mN/m
 

Section 10: STABILITY AND REACTIVITY

10.1 Reactivity
The mixture is stable under the recommended conditions of use and storage (section 7.2.).
10.2 Chemical stability
The product is stable when used and stored properly.
10.3 Possibility of hazardous reactions
They do not occur if the product is handled and stored as intended under the recommended conditions.
10.4 Conditions to avoid
Avoid temperatures below 0°C
10.5 Incompatible Materials
The mixture reacts with galvanized steel and structural steel, producing hydrogen, which can form an explosive mixture with air.
10.6 Hazardous decomposition products
If used and stored properly, they do not occur - but can occur in the event of fire (section 5.2).
 

Section 11 : TOXICOLOGICAL INFORMATION

11.1 Information on hazard classes according to Regulation (EC) No. 1272/2008
Information on acute and/or delayed effects of exposure was obtained in toxicological studies.

Acute Toxicity

LD50 (oral) rat :> 2000 mg/kg body weight.

D50 (dermal) Rat:>2000 mg/kg body weight. C50 (inhalation) rat after 4 hours exposure:> 5.0 mg/l

Cauterization/irritation of the skin

It does not irritate the skin.

 

Serious eye damage/eye irritation No eye irritation.

Sensitization of the respiratory tract or skin May cause an allergic skin reaction.

Mutagenic effect on germ cells*.

Not applicable - the components of the mixture do not meet the classification criteria.

 

Carcinogenic effect*

Not applicable - the components of the mixture do not meet the classification criteria.

Reproductive toxicity*

Not applicable - the components of the mixture do not meet the classification criteria.

Toxic effects on target organs - single exposure* Not applicable - the components of the mixture do not meet the classification criteria.

Toxic effects on target organs - repeated exposure* Not applicable - the components of the mixture do not meet the classification criteria.

Aspiration hazard*

Not applicable - the components of the mixture do not meet the classification criteria.

* Classification based on the properties of the components of a mixture

11.2 Information about other hazards
11.2.1 Endocrine disrupting properties Assessment
The ingredients of the mixture have no endocrine disrupting properties.
11.2.2 Other information
Not applicable.
 

Section 12: ENVIRONMENTAL INFORMATION

12.1 Toxicity
Acute toxicity to rainbow trout (Oncorhynchus mykiss): C50 (after 96 h) > 100 mg/l Acute toxicity to Daphnia magna:EC50(after 48 h) > 100 mg/l Acute toxicity to algae (Pseudokirchneriella subcapitata): ErC50 (after 72 h) = 117.62 mg/l

EyC50 (after 72 hours) = 65.32 mg/l NOEC (after 72 hours) = 32 mg/l

Toxicity for the ciliate (Lemna minor L.)

Growth inhibition ErfC50 after 168 h = 120.79 mg/l (number of members) Growth inhibition ErbC50 after 168 h > 320 mg/l (dry weight) Biomass growth inhibition EyfC50 after 168 h = 42.76 mg/l (number of members) Biomass growth inhibition EybC50 after 168 h = 106.58 mg/l (dry weight) NOEC is 10 mg/l

The LOEC value is 32 mg/l.

Toxicity for birds

Acute oral toxicity to Japanese quail (Coturnix coturnix japonica): LD50 > 2000 mg/kg body weight.

Toxicity for bees

Oral toxicity:LD50 is 100 μg/bee (glyphosate)Acute contact toxicity: LD50 is > 100 μg/bee (glyphosate)

Toxicity to earthworms and effects on earthworm reproduction LC50 after 7 and 14 days is > 1000 mg/kg body weight of substrate

12.2 Persistence and degradability
Glyphosate

Hydrolysis in water: does not hydrolyze

hotolytic degradation:DT50is 33 days (pH=5) Aerobic degradability in soil DT50:12 days

Photolysis in soil DT50 is 96 days

Aerobic and anaerobic transformations in aquatic sediments: DT50 (water-sediment) - 87 days

12.3 Bioaccumulative potential
The active substance glyphosate contained in the mixture is not bioaccumulative. Bioconcentration in fish:

ioconcentration factor for glyphosate:BCF= 0.5 Octanol/water partition coefficient - see section 9.1.

12.4 Mobility in soil
For surface tension, see section 9.2.

The active ingredient glyphosate is not mobile in the soil.

Adsorption coefficient for organic carbon at equilibrium (for glyphosate): Koc = 21699 ml/g

 

Equilibrium desorption coefficient (for glyphosate): Kdes = 245 (for sandy loam soil)

 

12.5 Results of the PBT and vPvB assessment
The substances in the mixture do not meet the criteria for classification as PBT or vPvB in accordance with Annex XIII of REACH.
12.6 Endocrine disruptors Properties
The components of the mixture have no endocrine disrupting properties for the environment.
12.7 Other harmful effects
The product does not contribute to global warming or the destruction of the ozone layer.
 

Section 13: NOTES ON DISPOSAL

13.1 Waste disposal methods
The holder of mixed waste and packaging waste is obliged to treat the waste in a manner that complies with the rules laid down in the Act on the Management of Packaging and Packaging Waste, the Waste Act and environmental protection regulations.

 

The resulting mixture and the packaging waste must be stored, transported and recycled, including material recycling, or disposed of in accordance with the provisions of the Waste Act and the corresponding ordinances.

 

Rinse the empty mixing containers three times with water and pour the rinsing water into the spray liquid container and treat as application liquid.

 

It is prohibited to use the empty packaging of the crop protection product for other purposes. Dispose of unused crop protection products and contaminated packaging at an authorized collection point for hazardous waste.

The waste must be classified using the appropriate codes and designations in accordance with the applicable waste catalog.

 

The disposal of waste into the ground, drains, rivers and bodies of water is prohibited.

National legislation that meets the requirements of existing European Union directives:

Act of June 13, 2013 on the management of packaging and packaging waste (OJ 2020, No. 1114).

Act of December 14, 2012 on Waste (Journal of Laws 2020, item 797 with amendments).

Ordinance of the Minister of Climate Action of January 2, 2020 on the Waste Catalogue (Journal of Laws of 2020, item 10).

 

Section 14: TRANSPORT INFORMATION

14.1 UN number or ID number
The mixture is not a dangerous good in the sense of the RID/ADR regulations.
14.2 UN proper shipping name
Not applicable.
14.3 Transport hazard class(n)
Not applicable.
14.4 Pack group
Not applicable.
14.5 Environmental risks
Not applicable.
14.6 Special precautions for users
Use personal protective equipment in accordance with section 8 when handling the load.
14.7 Transport of bulk goods by sea in accordance with IMO instruments
Not applicable.
 

Section 15: LEGAL REGULATIONS

15.1 Regulations on safety, health and environmental protection/specific
Legislation for the substance or mixture
- Act of February 25, 2011 on chemical substances and their mixtures (Journal of Laws of 2020, item 2289);

- Act of March 8, 2013 on Plant Protection Products (Dz. U. of 2020, item 2097, with amendments);

- Regulation (EC) No 1107/2009 of the European Parliament and of the Council of October 21, 2009 concerning the placing of plant protection products on the market and repealing Council Directives 79/117/EEC and 91/414/EEC (OJ L 309/1, 24.11.2009, amended),

- Regulation (EC) No. 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No. 793/93, Commission Regulation (EC) No 1488/94, Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC (Official Journal of the EU L 396/1 of 30.12.2006, with the exception of Regulation (EC) No 1907/2006).

in the corrected and amended version);

- Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (Official Journal of the EU L 353/1 of 31.12.2008, as amended);

- Commission Regulation (EC) No 286/2011 of 10 March 2011 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labeling and packaging of substances and mixtures (Official Journal of the EU L 83/1 of 30.03.2011);

- Regulation (EC) No 1005/2009 of the European Parliament and of the Council of September 16, 2009 on substances that deplete the ozone layer (Official Journal of the EU L 286/1 of 31.10.2009, as amended);

- COMMISSION REGULATION (EU) 2018/605 of April 19, 2018 amending Annex II to Regulation (EC) No 1107/2009 by establishing scientific criteria for the determination of endocrine disrupting properties

- Government statement of February 19, 2019 on the entry into force of the amendments to the annexes

A and B of the European Agreement concerning the International Carriage of Goods by Road

of Dangerous Goods (ADR), which was drawn up in Geneva on September 30, 1957. (Journal of Laws 2019 pos.

769).

15.2 Assessment of chemical safety
Evaluated as a plant protection product.

 

SECTION 16: OTHER INFORMATION
Explanation of abbreviations
Skin corr. 1B          - Skin corrosion/irritation - Category 1BEye damage. 1   - Serious eye damage/eye irritation - Category 1Aquatic Chronic 2 - Chronic water hazard, category 2.Aquatic Chronic 3 - Chronic aquatic hazard, Category 3.H314 - Causes severe skin burns and eye damage. H318 - Causes serious eye damage.H411 - Toxic to aquatic life with long lasting effects.H412 - Harmful to aquatic life with long lasting effects.Education:

Before handling the product, the user should be familiar with this safety data sheet as well as with the occupational safety regulations for handling chemicals and, in particular, have received appropriate training resulting from the provisions of the Labor Act and the Act on Plant Protection Products.

Data sources:

- Internal studies: physico-chemical, toxicological, ecotoxicological and environmental effects for the mixture,

- Assessment report for the active substance glyphosate - European Commission document No. Glyphosate

6511/VI/99-endg. of January 21, 2002;

 

Evaluation of the information:

The information determined in accordance with Chapter 1 of Title II of CLP has been compiled using the classification criteria for each hazard class, taking into account the further differentiation contained in Annex I of CLP. and taking into account the results of our own trials carried out for the plant protection product assessed. In assessing the available information for classification, the form/state of aggregation in which the mixture is placed on the market and in which it can reasonably be used has been taken into account.

Additional information:

Further information is available from the manufacturer - contact as in subsection 1.3.

This safety data sheet has been prepared in accordance with Commission Regulation (EU) 2020/878 of 18 June 2020 amending Annex II to Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorization and Restriction of Chemicals and Preparations.

Chemicals (REACH).

 

The information is based on our current knowledge and experience and is given in good faith to describe the product in terms of safety. It cannot be interpreted as a guarantee of properties or quality features. It is the responsibility of the recipient and user to ensure a safe workplace and to comply with all applicable regulations.

 

Commas in numerical data define decimal places.
Amendments to KCh/H/56, 4th edition dated 04.08.2020Sections 1, 2, 3, 9, 11, 12, 14, 15, 16.

Description

AGROSAR 360 SL is a herbicide in the form of a concentrate for the preparation of an aqueous solution. Use it foliar to control couch grass and other monocotyledonous and dicotyledonous weeds (annual and perennial) before harvesting winter wheat and winter oilseed rape. Use after harvest and before post-harvest cultivation in apple, pear, cherry, plum, peach, apricot, gooseberry, chokeberry, black, red and white currants, in forest nurseries, when planting and reforesting Scots pine and deciduous tree species, in gardens, in allotments, around houses, along fences, on driveways.

AGROSAR® 360 SL    OPTIMAL PRODUCT IN TERMS OF USER SAFETY AND PROTECTION OF THE ENVIRONMENT

    • The advantage of AGROSAR® 360 SL over many other similar products is that it does not contain ethoxylated fatty amine (tallow amine), which is commonly used as an adjuvant in this type of formulation.

 

    • In AGROSAR® 360 SL, the ethoxylated fatty amine has been replaced by a new generation internal adjuvant which, together with other surfactants, forms a unique system.
      This supports the effect of the active ingredient by optimizing the adhesion of the spray droplet to the leaf surface and covering the surface of the leaf blade better and more evenly with the working fluid. The result is an increase in the penetration area for maximum utilization of the active ingredient potential.

 

It should be emphasized here that the additives in a product influence its quality, effectiveness, shelf life and the lack of toxicity of the preparation. The frequently used ethoxylated fatty amine (tallow amine) has specific toxicological effects on aquatic organisms. The substitution of tallow amine by the use of a new generation of adjuvants has significantly improved the toxicological properties of AGROSAR 360 SL and its classification, particularly with regard to ecotoxicology and environmental impact.

    • The adjuvant used in the product AGROSAR® 360 SL is a mixture that does not contain any substances that are considered to be very persistent or highly bioaccumulative (so-called PBT or vPvB).

 

    • AGROSAR® 360 SL is not classified as dangerous for the environment and is therefore not labeled with the GHS 09 pictogram (according to Regulation (EC) No 1272/2008 of 16 December 2008 on classification, labeling and packaging of substances and mixtures) or the hazard symbol N, which distinguishes it from glyphosate-containing products available on the market.

 

 

Additional Information

Weight N/A
L

1, 5

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    Effectief middel zoals beschreven in website!

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